Synergy: More Than the Sum of Its Parts
Individually, lecithin and chitosan already provide strong crop protection. Lecithin enhances membrane disruption and spreadability, while chitosan delivers direct antifungal action and plant defense elicitation. When combined, their activities complement each other: lecithin weakens the fungal membrane, while chitosan binds and destabilizes it, amplifying antifungal efficacy.
Even more importantly, when mixed in water under acidic conditions (pH < 6.5), a remarkable process occurs:
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Electrostatic interaction – The positively charged –NH₃⁺ groups of chitosan bind to the negatively charged phosphate groups of lecithin.
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Nanostructure formation – Complexes resembling liposomes or vesicles are formed, capable of encapsulating bioactive molecules.
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Enhanced solubility and stability – Lecithin stabilizes chitosan in solution (preventing precipitation), while chitosan increases the stability of lecithin vesicles by acting as a protective coating.
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Improved plant uptake – These complexes are able to penetrate the cuticle more effectively, delivering chitosan deeper into the leaf tissue.